بررسی حذف استامینوفن از محلول آبی به روش پراکسی الکتروشیمیایی
فصلنامه علمی پژوهشی بهداشت در عرصه,
دوره 10 شماره 3 (1401),
18 March 2023
,
صفحه 1-10
https://doi.org/10.22037/jhf.v10i3.39207
چکیده
زمینه و اهداف: ترکیبات دارویی ازجمله استامینوفن ازطریق فاضلابهای شهری و صنعتی وارد محیط زیست میشوند. حضور این مواد در مقادیر بسیار کم اثرات نامطلوبی بر سلامتی ایجاد میکند. هدف از این تحقیق بررسی کارایی حذف استامینوفن از محلول آبی توسط رآکتور ناپیوسته پراکسی الکتروشیمیایی مرکب از الکترودهای روی-مس و پراکسید هیدروژن میباشد.
مواد و روشها: این تحقیق مطالعه تجربی آزمایشگاهی است. نمونه آب داراي استامینوفن تهيه و کارايي حذف درحالت مختلف متغيرهايpH (8-4)،زمان واکنش (90-30 دقيقه)، غلظت استامینوفن (200-50 میلیگرم بر لیتر)، چگالي جريان (9-3 میلیآمپر بر سانتیمتر مربع) و غلظت پراکسید هیدروژن (1/5-0/5 میلیگرم بر لیتر) مورد بررسي قرارگرفت. تعیین غلظت استامینوفن توسط دستگاه كروماتوگرافى مايع با عملكرد بالا در طول موج 360 نانومترانجامگرفت. ملاحظات اخلاقی در تمام مراحل اجرای مطالعه رعایت شد.
یافتهها: میزان حذف 50 میلیگرم بر لیتر استامینوفن در شرایط بهینه فاصله بین الکترودها 2 سانتيمتر، چگالي جريان الکتریکی 9 میلی آمپر بر سانتیمتر مربع، زمان الكتروليز 30 دقيقه و pH معادل 4، 63 درصد در سيستم الكتروشيميايي بدست آمد. مقدار حذف استامینوفن در غلظت 1/5 میلیگرم بر لیتر پراکسید هیدروژن، چگالي جريان الکتریکی 9 میلیآمپر بر سانتیمتر مربع، زمان 30 دقيقه، pH بهینه معادل 4 و غلظت 50 میلیگرم در لیتر استامینوفن 100 درصد در سيستم پراکسی الکتروشیمیایی بدست آمد.
نتیجهگیری: براساس این نتایج روش پراكسي الكتروشیمیایی، بهعنوان فنآوری اکسیداسیون پیشرفته امیدبخش دوستدار محیط زیست، در حذف آنتيبيوتيك استامینوفن از محلولهای آبی كارآئي مناسبي دارد.
- استامینوفن، پراکسی الكتروشیمیایی، پراکسیدهیدروژن، دارو
ارجاع به مقاله
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